I am assigned to design a water gas shift reactor to shift the h2. Modeling and simulation of watergas shift reactors. Kinetic modeling of low temperature watergas shift reaction. I am trying to design a packed bed reactor for a low temperature shift reaction. Nov 08, 2007 this work analyzes the water gas shift reactor design as component of the co cleanup system of the ethanol processor for h 2 production applied to pem fuel cells. Catalysts free fulltext recent advances in structured catalysts. This presentation does not contain any proprietary, confidential, or otherwise restricted information. Zeolite membrane reactor for hightemperature watergas shift. In this study, a water gas shift membrane reactor containing both a co2selective polymeric membrane and a commercial cuznoal2o3 catalyst was developed for hydrogen processing for fuel cells, especially for the protonexchange membrane fuel cells pemfcs.
Pilot water gas shift membrane device for hydrogen from coal tom barton western research institute 511. Water gas shift in applications where scrubbed syngas hydrogencarbon monoxide h2co ratio must be increasedadjusted to meet downstream process requirements, the syngas is passed through a multistage, fixedbed reactor containing shift catalysts to convert co and water into additional h2 and carbon dioxide co2 according to the following reaction known as the water gas shift wgs reaction. Kinetics and reactor modeling of a high temperature water. The lts shift reactor operates at a range of 200250 c.
Evaluation of alternate water gas shift configurations for. Water gas shift reaction kinetics and reactor modeling for. Modeling and simulation of water gas sh ift reactor. There are number of materials capable of catalyzing the watergas shift reaction, which are divided in two main classes that is the ironbased catalysts and the copperbased catalysts. With the high demand for clean fuel and the critical role of the water gas shift reaction in hydrogen fuel cells, the development of water gas shift catalysts for the application in fuel cell technology is an area of current research interest. Department of energy laboratory operated by midwest research institute battelle contract no. Process intensification with integrated watergasshift. Design of water gas shift converter student cheresources.
Carbon monoxide and hydrogen if they are present in the mole ratio of 1. Gasliquidsolid reactor design february 1, 1979 edition. Steadystate simulation of a sour water gas shift reactor. Complete the proofofconcept demonstration using the lab membrane reactor. However, its application as an alternative energy source is limited due to several constraints such as lack of technical. Novel water gas shift catalysts commercial water gas shift wgs lts catalysts. The justification of such a system would be improved efficiency for the overall hydrogen production. Design of watergas shift reactors journal article osti. Water gas shift reaction an overview sciencedirect topics. Jan 23, 2008 water gas shift reactor posted in student. Its purpose is to produce hydrogen and to reduce the level of co for final cleanup by preferential oxidation.
This configuration offers a lot of design flexibility because the material that. This shift steam is taken from an intermediate extraction point in the steam turbine. This project will develop hydrogenselective membranes for an innovative watergasshift reactor that improves gas separation. Kinetic study of high temperature water gas shift reaction. How do you design a high temperature water gas shift reactor. Reactor design is a vital step in the overall design of a process. Madeira, for giving me the greatest opportunity to participate in this field of research, for his. In the carbon based hydrogen production, water gas shift reaction is the intermediate step used for hydrogen enrichment and co reduction in the synthesis gas. A 1d dynamic model of a sour water gas shift reactor. Hi,i need to design a water gas shift reactor as part of my design project. Thermodynamic model formulation the thermodynamic model proposed in this work is based on gibbs free energy minimization which implies that the system has reached an equilibrium state. Kinetic, experimental, modeling, and simulation studies of a catalytic high temperature 673. Pdf the progress in water gas shift and steam reforming. The book explains the development of catalysts for water gas shift wgs reaction at.
Discover the best natural gas energy in best sellers. Nitrogen gas was used as an inert diluent to make up the total pressure to 1 atm. Development of novel watergasshift membrane reactor. Conduct the prototype membrane reactor demonstration for a fuel cell. Copper based medium temperature water gas shift catalyst is ideal for use in fuel cell and other distributed hydrogen production applications. Draft preapplication safety evaluation report for the modular hightemperature gas cooled reactor nureg38 was written in early 1989. Experimental and modeling work ii abstract the main goal of this work was to perform the experimental study of a watergas shift wgs reaction and produced hydrogen separation unit using a pd membrane. An innovative process scheme to produce methanol from carbon dioxide is here presented and assessed via simulation. Watergas shift wgs operation of precombustion co2 capture. Search the worlds most comprehensive index of fulltext books. This requires development of more active lowtemperature catalysts and advanced reactor concepts to overcome limitations related to low co conversions in the range 250350 c. The watergas shift reaction wgsr describes the reaction of carbon monoxide and water. Biological watergas shift conversion of carbon monoxide to hydrogen milestone completion report wade a. Packed bed membrane reactor for the watergas shift reaction.
Analysis of design variables for watergasshift reactors by. Amos national renewable energy laboratory 1617 cole boulevard golden, colorado 8040393 nrel is a u. Winston ho department of chemical and biomolecular engineering. Modeling and simulation of water gas shift reactor.
Catalyst development for watergas shift gek gasifier. In the mid1980s, doe turned to a smaller modular design a modular htgr with an annular core and steel rpv, and a conceptual design was completed in 1987. Fecr 2o 3 interstage cooling high temperature shift low temperature shift 100 200 300 400 500 600 6. Please suggest me some of books to read about model organism. The reverse water gas shift reaction rwgs reaction was discovered in the 19th century as a method of producing water from carbon dioxide and hydrogen, with carbon monoxide as a side product. The book explains the development of catalysts for water gas shift wgs reaction at different temperatures and steamco ratios, and also discussing the effect of different dopants on the wgs activity of iron oxide and the promotion and inhibition roles of the dopants on the wgs activity of iron oxide are explained. In a batch reactor, the reagents are added together and allowed to react for a given amount of time. Find the top 100 most popular items in amazon books best sellers.
It is theref ore importa nt to design th e h 2 oco rati o at the inlet. By douglas falleiros barbosa lima, fernando ademar zanella, marcelo kaminski lenzi and papa matar ndiaye. Analysis of design variables for watergasshift reactors by modelbased optimization article in journal of power sources 1731. The watergas shift reaction shift conversion is necessary because the gaseous product from a gasifier generally contains large amounts of carbon monoxide and hydrogen, plus lesser amounts of other gases. How to determine the optimum ld ratio for a water gas shift reactor. Continue to synthesize and characterize improved membranes for the reactor. Any steam extracted for the shift is not expanded in the turbine to produce power, therefore the water gas shift step is typically viewed as a burden on the steam cycle. In adiabatic operation mode, for achieving a co composition of 0.
Biological watergas shift conversion of carbon monoxide to. Copper based medium temperature water gas shift catalyst. Design of experiments on the kinetics of the watergas shift. In most hydrocarbon processors, the water gas shift reactor is the biggest and heaviest component because the reaction is relatively slow compared to the other reactions and is inhibited at higher temperatures by thermodynamics. Hydrogenselective membranes for highpressure hydrogen separation. The book explains the development of catalysts for water gas shift. New catalyst for the h 2 production by water gas shift reaction processes tesi di dottorato di ricerca in chimica industriale settore chim04 presentata da dr. Catalysts for fuel cell application would need to operate at low temperatures. Methanol production from co2 via reversewatergasshift. Introduction a watergasshift wgs reactor for the conversion of carbon monoxide co and water to. Subsequent chapters are devoted to reactor sizing and modelling in some simple situations, and more detailed coverage of the design and operation of the principal reactor types.
For more than 90 years after its first industrial application, many issues in respect of the catalyst, process configuration, reactor design, reaction. From the analysis of variance of these sixteen runs it can be shown that the temkin mechanism for the water gas shift reaction cannot represent the data within the experimental accuracy. It is important to ensure that the equipment specified will be capable of achieving the desired yields and selectivity. Co ratio to be 2, and i have researched that in order to produce methanol, only one single adiabatic high temperature water gas. Find, read and cite all the research you need on researchgate. The wgs reactor constitutes the element of greater volume of the processor motivating its optimization. Analysis of design variables for watergasshift reactors. This project is in response to a requirement for a system that combines water gas shift technology with separation technology for coal derived synthesis gas. Help us write another book on this subject and reach those readers. Pdf modeling and simulation of water gas shift reactor. Pilot water gas shiftmembrane device for hydrogen from coal. In my humble opinion, first you must read a book higman gasification for. Scheme of the reactor thermodynamic modeling of water gas shift reaction in supercritical water. In this configuration, the syngas stream, composed by co, co 2, and h 2 and fed to the methanol synthesis reactor, is produced by means of a reversewatergasshift by which a co 2 stream is partially converted in carbon monoxide.
The wgs reactor currently represents the largest volume of any catalyst in a fuel processor due to the slow. Hydrogen production in a large scale watergas shift pdbased. The recent concerns about clean energy and hydrogen production have led to a renewed interest in the water gas shift reaction over the past few years. The watergas shift reaction plays a key role in hydrogen production. Packed bed membrane reactor for the water gas shift reaction. Shah, february 1, 1979, mcgrawhill education edition, hardcover in english. A sulfur and halidetolerant water gas shift catalyst and a sulfurtolerant dense metallic.
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